In an interdisciplinary approach to the design and operation of such processes, essential principles of Green Chemistry are realized, such as using long-chain olefins as model representatives of renewable raw materials, highly effi cient catalysts, and green solvents, linked with process optimization to improve energy and material efficiency. Experts from different fields addressed all steps of the development process, from the description of the reactions on the molecular level via thermodynamics and the design of efficient separation processes to the operation of entire miniplants for liquid multiphase.